This is equivalent to the server's TLSCACertificateFile option. As noted in the TLS Configuration section, a client typically may need to know about more CAs than a server, but otherwise the same considerations apply.
This is equivalent to the server's TLSCACertificatePath option. The specified directory must be managed with the OpenSSL c_rehash utility as well. If using Mozilla NSS, <path> may contain a cert/key database.